(N-Butyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
نویسندگان
چکیده
The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra-hedrally coordinated Sn atom, as the dithio-carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra-hedral geometry about the metal atom are evident with the widest C-Sn-S angle being 117.26 (5)°. In the crystal, mol-ecules are linked by C-H⋯S inter-actions, which generate helical supra-molecular chains along the b axis.
منابع مشابه
(N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol-ecules in the asymmetric unit and each features a tetra-hedrally coordinated Sn(IV) atom as the dithio-carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn⋯S(thione) = 3.1477 (6) and 2.9970 (5) Å for the independent mol-ecules], distortions from ...
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متن کامل(N-sec-Butyl-N-n-propyldithiocarbamato-κ2 S,S′)triphenyltin(IV)
The Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], is penta-coordinated by two S atoms, derived from an asymmetrically coordinating dithio-carbamate ligand, and three ipso-C atoms. The coordination geometry is inter-mediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intra-molecular C-H⋯S contacts preclude the S ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011